In elemental state, oxygen is a gas in the atmosphere and is dissolved in water. The amount of relatively reactive oxygen elemental remains constant only in long run, because O2 producing plants replace much as of aerobic breathing creatures as well as other combustion processes is used again (oxygen for energy). Without this biological cycle O2 would only occur in compounds, ie elemental O2 exists in a dynamic equilibrium.
Almost all living organisms need O2 to live (typically give plants during photosynthesis but more O2 from than they consume). You see him mostly by breathing in air, or by absorption of water (dissolved oxygen). In high concentrations, however, it is toxic to most living things.The metastable, high-energy and reactive allotrope of three O2 atoms (O3) is called ozone. Atomic oxygen, ie O2 in form of free, single O2 atoms, is stable before only under extreme conditions, such as in vacuum of space or in hot stellar atmospheres. However, it has a significant meaning as a reactive intermediate in many reactions of atmospheric chemistry.
Some oxygen-rich inorganic compounds such as potassium permanganate, potassium nitrate (saltpeter), potassium chlorate and potassium chromate enter upon heating or reaction with reducing agents from oxygen. A further possibility of producing O2 in laboratory, is the decomposition of hydrogen peroxide on platinum-plated nickel foil. Pure O2 can be obtained by electrolysis of 30% potassium hydroxide solution of nickel electrodes. It Hydrogen and O2 are separated.
O2 is slightly soluble in water. The solubility depends on the pressure and the temperature. It increases with decreasing temperature and increasing pressure. At 0 degrees C and an O2 partial pressure of air of 212 hPa dissolve in pure water 14.16 mg / l oxygen. In oxygen-gas discharge Spectrum, the molecular orbitals of O2 are stimulated to emit light. The operating conditions are a pressure of 5-10 mbar, a high voltage of 1.8 kV, a current of 18 mA and a frequency of 35 kHz. During the recombination of ionized gas molecules, the characteristic color spectrum is emitted. In this case, a small part, caused reversibly formed by the supply of energy ozone.
With the discovery of O2 its meaning was not clear during combustion. The Frenchman Antoine Lavoisier found in his experiments that during combustion does not escape phlogiston, but O2 is bound. By weighing it demonstrated that a substance after combustion was not easier but harder. This was caused by the additional weight of ingested during the combustion process oxygen.
For O2 recovery after Claude process air by means of compressors to 5-6 bar is compressed, cooled and then removed by first filter of carbon dioxide, humidity, and other gases. The compressed air is cooled by flowing past gases from the process to a temperature near the boiling point. It is then expanded in turbines. A portion of energy used for compression can again be recovered. This is the method -. In contrast to Linde process, in which no energy is recovered - a lot more efficient.
Occupation of energy levels of molecular orbitals of O2 in ground and excited states. In ground state the spins of two valence electrons of Hund's rule are arranged in parallel in obedience. It is a triplet state with the term symbol 3g. It is the state with the lowest energy. Through the two unpaired electrons, the two orbitals are half occupied. This caused some characteristic properties, such as the diradical character and the paramagnetism of O2 molecule.
The separation takes place initially at 5-6 bar in so-called medium pressure column. The resulting oxygen-enriched liquid is then (pressure about 0.5 bar) further separated in low pressure column. Through the liquid O2 of low pressure column, gaseous nitrogen of high pressure column is passed. It liquefies this and heated with the votes condensation heat the liquid. The more volatile nitrogen is discharged and preferably remains purified liquid oxygen. This still contains the noble gases krypton and xenon, which are separated in a separate column.
Almost all living organisms need O2 to live (typically give plants during photosynthesis but more O2 from than they consume). You see him mostly by breathing in air, or by absorption of water (dissolved oxygen). In high concentrations, however, it is toxic to most living things.The metastable, high-energy and reactive allotrope of three O2 atoms (O3) is called ozone. Atomic oxygen, ie O2 in form of free, single O2 atoms, is stable before only under extreme conditions, such as in vacuum of space or in hot stellar atmospheres. However, it has a significant meaning as a reactive intermediate in many reactions of atmospheric chemistry.
Some oxygen-rich inorganic compounds such as potassium permanganate, potassium nitrate (saltpeter), potassium chlorate and potassium chromate enter upon heating or reaction with reducing agents from oxygen. A further possibility of producing O2 in laboratory, is the decomposition of hydrogen peroxide on platinum-plated nickel foil. Pure O2 can be obtained by electrolysis of 30% potassium hydroxide solution of nickel electrodes. It Hydrogen and O2 are separated.
O2 is slightly soluble in water. The solubility depends on the pressure and the temperature. It increases with decreasing temperature and increasing pressure. At 0 degrees C and an O2 partial pressure of air of 212 hPa dissolve in pure water 14.16 mg / l oxygen. In oxygen-gas discharge Spectrum, the molecular orbitals of O2 are stimulated to emit light. The operating conditions are a pressure of 5-10 mbar, a high voltage of 1.8 kV, a current of 18 mA and a frequency of 35 kHz. During the recombination of ionized gas molecules, the characteristic color spectrum is emitted. In this case, a small part, caused reversibly formed by the supply of energy ozone.
With the discovery of O2 its meaning was not clear during combustion. The Frenchman Antoine Lavoisier found in his experiments that during combustion does not escape phlogiston, but O2 is bound. By weighing it demonstrated that a substance after combustion was not easier but harder. This was caused by the additional weight of ingested during the combustion process oxygen.
For O2 recovery after Claude process air by means of compressors to 5-6 bar is compressed, cooled and then removed by first filter of carbon dioxide, humidity, and other gases. The compressed air is cooled by flowing past gases from the process to a temperature near the boiling point. It is then expanded in turbines. A portion of energy used for compression can again be recovered. This is the method -. In contrast to Linde process, in which no energy is recovered - a lot more efficient.
Occupation of energy levels of molecular orbitals of O2 in ground and excited states. In ground state the spins of two valence electrons of Hund's rule are arranged in parallel in obedience. It is a triplet state with the term symbol 3g. It is the state with the lowest energy. Through the two unpaired electrons, the two orbitals are half occupied. This caused some characteristic properties, such as the diradical character and the paramagnetism of O2 molecule.
The separation takes place initially at 5-6 bar in so-called medium pressure column. The resulting oxygen-enriched liquid is then (pressure about 0.5 bar) further separated in low pressure column. Through the liquid O2 of low pressure column, gaseous nitrogen of high pressure column is passed. It liquefies this and heated with the votes condensation heat the liquid. The more volatile nitrogen is discharged and preferably remains purified liquid oxygen. This still contains the noble gases krypton and xenon, which are separated in a separate column.
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